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Aqueous Zn/MnO 2 batteries with their environmental sustainability and competitive cost, are becoming a promising, safe alternative for grid-scale electrochemical energy storage. Presented as a promising design principle to deliver a higher theoretical capacity, this work offers fundamental understanding of the dissolution–deposition mechanism of Zn/β-MnO 2 . A multimodal synchrotron characterization approach including three operando X-ray techniques (powder diffraction, absorption spectroscopy, and fluorescence microscopy) is coupled with elementally resolved synchrotron X-ray nano-tomography. Together they provide a direct correlation between structural evolution, reaction chemistry, and 3D morphological changes. Operando synchrotron X-ray diffraction and spectroscopy show a crystalline-to-amorphous phase transition. Quantitative modeling of the operando data by Rietveld refinement for X-ray diffraction and multivariate curve resolution (MCR) for X-ray absorption spectroscopy are used in a complementary fashion to track the structural and chemical transitions of both the long-range (crystalline phases) and short-range (including amorphous phases) ordering upon cycling. Scanning X-ray microscopy and full-field nano-tomography visualizes the morphology of electrodes at different electrochemical states with elemental sensitivity to spatially resolve the formation of the Zn- and Mn-containing phases. Overall, this work critically indicates that for Zn/MnO 2 aqueous batteries, the reaction pathways involving Zn–Mn complex formation upon cycling become independent of the polymorphs of the initial electrode and sheds light on the interplay among structural, chemical, and morphological evolution for electrochemically driven phase transitions. 

Abstract Copper (Cu) and iron (Fe) are essential micronutrients that are toxic when accumulating in excess in cells. Thus, their uptake by roots is tightly regulated. While plants sense and respond to local Cu availability, the systemic regulation of Cu uptake has not been documented in contrast to local and systemic control of Fe uptake. Fe abundance in the phloem has been suggested to act systemically, regulating the expression of Fe uptake genes in roots. Consistently, shoot-to-root Fe signaling is disrupted in Arabidopsis thaliana mutants lacking the phloem companion cell-localized Fe transporter, OLIGOPEPTIDE TRANSPORTER 3 (AtOPT3). We report that AtOPT3 also transports Cu in heterologous systems and contributes to its delivery from sources to sinks in planta. The opt3 mutant contained less Cu in the phloem, was sensitive to Cu deficiency and mounted a transcriptional Cu deficiency response in roots and young leaves. Feeding the opt3 mutant and Cu- or Fe-deficient wild-type seedlings with Cu or Fe via the phloem in leaves downregulated the expression of both Cu- and Fe-deficiency marker genes in roots. These data suggest the existence of shoot-to-root Cu signaling, highlight the complexity of Cu/Fe interactions, and the role of AtOPT3 in fine-tuning root transcriptional responses to the plant Cu and Fe needs. 

Abstract. The ocean mixed layer is the interface between the ocean interior and the atmosphere or sea ice and plays a key role in climate variability. It isthus critical that numerical models used in climate studies are capable of a good representation of the mixed layer, especially its depth. Here weevaluate the mixed-layer depth (MLD) in six pairs of non-eddying (1∘ grid spacing) and eddy-rich (up to 1/16∘) models from theOcean Model Intercomparison Project (OMIP), forced by a common atmospheric state. For model evaluation, we use an updated MLD dataset computed fromobservations using the OMIP protocol (a constant density threshold). In winter, low-resolution models exhibit large biases in the deep-waterformation regions. These biases are reduced in eddy-rich models but not uniformly across models and regions. The improvement is most noticeable inthe mode-water formation regions of the Northern Hemisphere. Results in the Southern Ocean are more contrasted, with biases of either sign remainingat high resolution. In eddy-rich models, mesoscale eddies control the spatial variability in MLD in winter. Contrary to a hypothesis that thedeepening of the mixed layer in anticyclones would make the MLD larger globally, eddy-rich models tend to have a shallower mixed layer at mostlatitudes than coarser models do. In addition, our study highlights the sensitivity of the MLD computation to the choice of a reference level andthe spatio-temporal sampling, which motivates new recommendations for MLD computation in future model intercomparison projects.